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H58532 4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
149923-10-4
Synonyms

Stock No. Size Price ($) Quantity Availability
H58532-AD 50ml 286.00
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4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD01319882

Chemical Properties

Formula
C7H6Cl2Zn
Formula Weight
226.41
Density
0.96
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Argon.
Solubility
Reacts with water.

Applications

4-Chlorobenzylzinc chloride used as a intermediate for pharmaceutical.

Notes

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Y. Fu; M. Yuan; X. Hu; Y. Yang; and H. Hou. 5-{2-(4-Chloro­phen­yl)-1-[2-(4-chloro­phen­yl)-1-(3,4,5-trimeth­oxy­phen­yl)eth­oxy]eth­yl}-1,2,3-trimeth­oxy­benzene. Acta Cryst.,2012, E68, o1007.

Zhi-Yong Peng; Fang-Fang Ma; Lv-Feng Zhu; Xiao-Min Xie; and Zhaoguo Zhang. Lewis Acid Promoted Carbon-Carbon Double-Bond Formation via Organozinc Reagents and Carbonyl Compounds. J. Org. Chem. 2009, 74 (17), 6855-6858.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335-H351

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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