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149923-10-4 - 4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58532 - Alfa Aesar

H58532 4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
149923-10-4
Synonyms

Size Price ($) Quantity Availability
50ml 122.00
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4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD01319882

Chemical Properties

Formula
C7H6Cl2Zn
Formula Weight
226.41
Density
0.96
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

4-Chlorobenzylzinc chloride used as a intermediate for pharmaceutical.

Notes

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Y. Fu; M. Yuan; X. Hu; Y. Yang; and H. Hou. 5-{2-(4-Chloro­phen­yl)-1-[2-(4-chloro­phen­yl)-1-(3,4,5-trimeth­oxy­phen­yl)eth­oxy]eth­yl}-1,2,3-trimeth­oxy­benzene. Acta Cryst.,2012, E68, o1007.

Zhi-Yong Peng; Fang-Fang Ma; Lv-Feng Zhu; Xiao-Min Xie; and Zhaoguo Zhang. Lewis Acid Promoted Carbon-Carbon Double-Bond Formation via Organozinc Reagents and Carbonyl Compounds. J. Org. Chem. 2009, 74 (17), 6855-6858.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P223-P210-P231+P232-P260u-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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