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77047-87-1 - Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - 2-Propylzinc bromide - H58536 - Alfa Aesar

H58536 Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
77047-87-1
Synonyms
2-Propylzinc bromide

Size Price ($) Quantity Availability
50ml 183.00
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Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD06200639

Chemical Properties

Formula
C3H7BrZn
Formula Weight
188.37
Density
0.963
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

Isopropylzinc bromide is employed in croos-coupling reactions.

Notes

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Literature References

Chong Han.; Stephen L. Buchwald. Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides. J. Am. Chem. Soc. 2009, 131 (22),7532-7533.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P210-P231+P232-P260-P201-P261-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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