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38111-44-3 - Phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58659 - Alfa Aesar

H58659 Phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
38111-44-3
Synonyms

Size Price ($) Quantity Availability
50ml 174.00
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Phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD01319861

Chemical Properties

Formula
C6H5BrZn
Formula Weight
222.39
Density
0.99
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

It is used in the cross-coupling reaction.

Notes

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Literature References

Tamio Hayashi.; Akihiro Yamamoto.; Toshiya Hagihara. Stereo- and regiochemistry in palladium-catalyzed nucleophilic substitution of optically active (E)- and (Z)-allyl acetates. J. Org. Chem. 1986, 51 (5),723-727.

Mario Rottländer.; Paul Knochel. Palladium-Catalyzed Cross-Coupling Reactions with Aryl Nonaflates:? A Practical Alternative to Aryl Triflates. J. Org. Chem. 1998, 63 (1),203-208.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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