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H58659 Phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
38111-44-3
Synonyms

Stock No. Size Price ($) Quantity Availability
H58659-AD 50ml 180.00
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Phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD01319861

Chemical Properties

Formula
C6H5BrZn
Formula Weight
222.39
Density
0.99
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Argon.
Solubility
Reacts with water.

Applications

It is used in the cross-coupling reaction.

Notes

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Literature References

Tamio Hayashi.; Akihiro Yamamoto.; Toshiya Hagihara. Stereo- and regiochemistry in palladium-catalyzed nucleophilic substitution of optically active (E)- and (Z)-allyl acetates. J. Org. Chem. 1986, 51 (5),723-727.

Mario Rottländer.; Paul Knochel. Palladium-Catalyzed Cross-Coupling Reactions with Aryl Nonaflates:? A Practical Alternative to Aryl Triflates. J. Org. Chem. 1998, 63 (1),203-208.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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