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312624-26-3 - 2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58695 - Alfa Aesar

H58695 2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
312624-26-3
Synonyms

Size Price ($) Quantity Availability
50ml 168.92
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2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671974

Chemical Properties

Formula
C3H4BrNZn
Formula Weight
199.36
Density
0.955
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

It is employed as a intermediate for pharmaceutical. Also used as efficient cyanide ion source for palladium-catalyst.

Notes

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Toshikatsu Takanami; Mikiko Hayashi; Hiroshi Chijimatsu; Wakaba Inoue; and Kohji Suda. Palladium-Catalyzed Cyanation of Porphyrins Utilizing Cyanoethylzinc Bromide as an Efficient Cyanide Ion Source. Org. Lett.,2005, 7(18), 3937-3940.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H300-H335-H314-H351

Highly flammable liquid and vapour. In contact with water releases flammable gas. Fatal if swallowed. May cause respiratory irritation. Causes severe skin burns and eye damage. Suspected of causing cancer.

Precautionary Statements: P210-P231+P232-P260-P201-P261-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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