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H58852 Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
7565-57-3
Synonyms

Stock No. Size Price ($) Quantity Availability
H58852-AD 50ml 161.00
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Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671993

Chemical Properties

Formula
C6H11BrZn
Formula Weight
228.44
Density
0.963
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Argon.
Solubility
Reacts with water.

Applications

It is used as primary and secondary intermediate.

Notes

Store at room temperature. Incompatible with strong oxidizing agents and acids.

Literature References

Maria F. Dalence-Guzmán.; Jörgen Toftered.; Viveca Thornqvist Oltner.; David Wensbo.; Martin H. Johansson. Synthesis of novel tetrahydroisoquinoline bronchodilators.Bioorg. Med. Chem. Lett. 2010, 20 (17),4999-5003.

Jie Wu , Yun Liao.; Zhen Yang. Synthesis of 4-Substituted Coumarins via the Palladium-Catalyzed Cross-Couplings of 4-Tosylcoumarins with Terminal Acetylenes and Organozinc Reagents.J. Org. Chem. 2001, 66 (10),3642-3645.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335-H336-H351

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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