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226570-68-9 - 4-Cyanobutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58897 - Alfa Aesar

H58897 4-Cyanobutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
226570-68-9
Synonyms

Size Price ($) Quantity Availability
50ml 203.85
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4-Cyanobutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD01316996

Chemical Properties

Formula
C5H8BrNZn
Formula Weight
227.41
Density
0.971
Sensitivity
Air Sensitive
Solubility
Reacts with water.

Applications

It is used as primary and secondary intermediate.

Notes

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Literature References

Jian Dai.; Jeanette L Sellers.; Ronald E Noftle. An efficient method for the synthesis of 3-alkylthiophenes bearing functional groups on the side chain: imides and amides. Synth. Met. 2003, 139 (1),81-88.

Mallesh Beesu.; Giuseppe Caruso.; Alex C. D. Salyer.; Karishma K. Khetani.; Diptesh Sil.; Mihiri Weerasinghe.; Hiromi Tanji.; Umeharu Ohto.; Toshiyuki Shimizu.; Sunil A. David. Structure-Based Design of Human TLR8-Specific Agonists with Augmented Potency and Adjuvanticity. J. Med. Chem. 2015.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H351-H302-H335

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Suspected of causing cancer. Harmful if swallowed. May cause respiratory irritation.

Precautionary Statements: P210-P260-P201-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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