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H59868 Malonyl dichloride, 97%

CAS Number
1663-67-8
Synonyms
Malonyl chloride

Stock No. Size Price ($) Quantity Availability
H59868-14 25g 119.00
H59868-22 100g 351.00
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Malonyl dichloride, 97%

MDL
MFCD00000735
EINECS
216-772-9

Chemical Properties

Formula
C3H2Cl2O2
Formula Weight
140.95
Boiling Point
53-55°/19mm
Flash Point
47°(117°F)
Density
1.449
Refractive Index
1.4650
Storage & Sensitivity
Ambient temperatures.
Solubility
Decomposes in water.

Applications

Malonyl Dichloride is primarily used an intermediate in the manufacture of pharmaceutical and agrochemical products.

Notes

Recommended storage temperature: 2 - 4°C. Incompatible with oxidizing agents.

Literature References

Sarah J. Spessard.; Brian M. Stoltz. Progress toward the Synthesis of Garsubellin A and Related Phloroglucins:? The Direct Diastereoselective Synthesis of the Bicyclo[3.3.1]nonane Core. Org. Lett. 2002, 4 (11),1943-1946.

H.-G. Mack.; H. Oberhammer.; C.O.Della Védova. Gas-phase structure and conformational properties of malonyl dichloride, ClC(O)CH2C(O)Cl. J. Mol. Struct. 1995, 346

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H314

Flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
774044
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2917.19
TSCA
Yes

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