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H60034 Iron(III) trifluoromethanesulfonate, tech. 90%

CAS Number
63295-48-7
Synonyms

Stock No. Size Price ($) Quantity Availability
H60034-MD 250mg 14.00
H60034-03 1g 42.60
H60034-06 5g 188.00
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Iron(III) trifluoromethanesulfonate, tech. 90%

MDL
MFCD15144785

Chemical Properties

Formula
C3F9FeO9S3
Formula Weight
503.04
Melting point
183°
Flash Point
110°(230°F)
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in water, methanol and acetonitrile.

Applications

Iron(III) triflate is used as an efficient catalyst in the synthesis of 2,3-unsaturated-O-glycosides from 2,4,6-tri-O-acetyl-D-glucal. It is also involved in the synthesis of a variety of beta-enamino ketones and esters.

Notes

Moisture sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Xolin, A.; Stevenin, A.; Pucheault, M.; Norsikian, S.; Boyer, F. D.; Beau, J. M. Glycosylation with N-acetyl glycosamine donors using catalytic iron (iii) triflate: from microwave batch chemistry to a scalable continuous-flow process. Org Chem Front 2014, 1 (8), 992-1000.

Feng, C. L.; Chu, N. N.; Zhang, S. G.; Cai, J.; Chen, J. Q.; Hu, H. Y.; Ji, M. Solvent-free synthesis of beta-enamino ketones and esters catalysed by recyclable iron (III) triflate. Chem. Pap. 2014, 68 (8), 1097-1103.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2904.99
TSCA
No

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