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63295-48-7 - Iron(III) trifluoromethanesulfonate, tech. 90% - H60034 - Alfa Aesar

H60034 Iron(III) trifluoromethanesulfonate, tech. 90%

CAS Number

Size Price ($) Quantity Availability
250mg 13.50
1g 43.00
5g 180.00
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Iron(III) trifluoromethanesulfonate, tech. 90%


Chemical Properties

Formula Weight
Melting point
Flash Point
Moisture Sensitive
Soluble in water, methanol and acetonitrile.


Iron(III) triflate is used as an efficient catalyst in the synthesis of 2,3-unsaturated-O-glycosides from 2,4,6-tri-O-acetyl-D-glucal. It is also involved in the synthesis of a variety of beta-enamino ketones and esters.


Moisture sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Xolin, A.; Stevenin, A.; Pucheault, M.; Norsikian, S.; Boyer, F. D.; Beau, J. M. Glycosylation with N-acetyl glycosamine donors using catalytic iron (iii) triflate: from microwave batch chemistry to a scalable continuous-flow process. Org Chem Front 2014, 1 (8), 992-1000.

Feng, C. L.; Chu, N. N.; Zhang, S. G.; Cai, J.; Chen, J. Q.; Hu, H. Y.; Ji, M. Solvent-free synthesis of beta-enamino ketones and esters catalysed by recyclable iron (III) triflate. Chem. Pap. 2014, 68 (8), 1097-1103.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code


  • A11879

    2,3-Dichloro-5,6-dicyano-1,4-benzoquinone, 98+%
  • A12139

    Phenylacetylene, 98+%
  • A12646

    Triethylamine, 99%
  • A12949

    Triphenylcarbenium tetrafluoroborate, 98%
  • L12066

    Methyl 2-dimethylaminobenzoate, 95%

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