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Iron(III) triflate is used as an efficient catalyst in the synthesis of 2,3-unsaturated-O-glycosides from 2,4,6-tri-O-acetyl-D-glucal. It is also involved in the synthesis of a variety of beta-enamino ketones and esters.
Xolin, A.; Stevenin, A.; Pucheault, M.; Norsikian, S.; Boyer, F. D.; Beau, J. M. Glycosylation with N-acetyl glycosamine donors using catalytic iron (iii) triflate: from microwave batch chemistry to a scalable continuous-flow process. Org Chem Front 2014, 1 (8), 992-1000.
Feng, C. L.; Chu, N. N.; Zhang, S. G.; Cai, J.; Chen, J. Q.; Hu, H. Y.; Ji, M. Solvent-free synthesis of beta-enamino ketones and esters catalysed by recyclable iron (III) triflate. Chem. Pap. 2014, 68 (8), 1097-1103.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.