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16420-13-6 - Dimethylthiocarbamoyl chloride, 95% - H60104 - Alfa Aesar

H60104 Dimethylthiocarbamoyl chloride, 95%

CAS Number
16420-13-6
Synonyms

Size Price ($) Quantity Availability
25g 56.60
100g 189.00
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Dimethylthiocarbamoyl chloride, 95%

MDL
MFCD00004919

Chemical Properties

Formula
C3H6ClNS
Formula Weight
123.60
Melting point
39-43°
Boiling Point
90-95°
Flash Point
98°(208°F)
Sensitivity
Moisture Sensitive
Solubility
Soluble in chloroform and tetrahydrofuran.

Applications

Dimethylthiocarbamoyl chloride is used as an intermediate in the synthesis of pharmaceuticals. It finds application in chemoselective deoxygenation of pyridine-N-oxides. It is also used as a starting reagent in the synthesis of dimethylthiocarbamates.

Notes

Store in cool place. Moisture sensitive. Incompatible with strong oxidizing agents, amines and strong bases. Reacts violently with water.

Literature References

Zaim, O.; Tuzun, N. S.; Cevik, B.; Ozcan, H.; Boz, E. Synthesis, reactions and DFT study of tropolone N,N-dimethylthiocarbamate. Tetrahedron 2015, 71 (33), 5391-5398.

Gandhi, M. R.; Yamada, M.; Kondo, Y.; Sato, R.; Hamada, F. Synthesis and Characterization of Dimethylthiocarbamoyl-Modified Thiacalix[n]arenes for Selective Pd(II)-Ion Extraction. Ind. Eng. Chem. Res. 2014, 53 (7), 2559-2565.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H314-H318-H317

Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
635823
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2930.20
TSCA
Yes

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