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1365531-98-1 - (R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4',6,6'-tetramethoxybiphenyl, 97+% - (R)-DTBM-Garphos - (R)-(4,4',6,6'-Tetramethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine] - H60112 - Alfa Aesar

H60112 (R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4',6,6'-tetramethoxybiphenyl, 97+%

CAS Number
1365531-98-1
Synonyms
(R)-DTBM-Garphos
(R)-(4,4',6,6'-Tetramethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine]

Size Price ($) Quantity Availability
250mg 191.58
1g 689.07
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(R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4',6,6'-tetramethoxybiphenyl, 97+%

MDL
MFCD20265636

Chemical Properties

Formula
C76H108O8P2
Formula Weight
1211.61
Sensitivity
Air Sensitive
Solubility
Insoluble in water.

Notes

Incompatible with light and oxidizing agents. Store in a cool place.

Literature References

Ch Durga Prasad.; Shah Jaimin Balkrishna.; Amit Kumar.; Bhagat Singh Bhakuni.; Kaustubh Shrimali.; Soumava Biswas.; Sangit Kumar. Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Chalcogenides from Arenes and Diaryl Dichalcogenides. J. Org. Chem. 2013, 78 (4), 1434-1443.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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