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Benzyl chloromethyl ether is employed in the introduction of benzoyloxy- and hydroxymethyl groups.
Dane A. Goff.; Ralph N. HarrisIII.; Jeffrey C. Bottaro.; Clifford D. Bedford. Cleavage of methoxymethyl ethers with boron trichloride. A convenient, versatile preparation of chloromethyl ether derivatives. J. Org. Chem. 1986, 51 (24),4711-4714.
Arthur J. Hill.; DeWitt T. Keach. Some Ether-Substituted Derivatives Of Diethyl Malonate And Barbituric Acid.J. Am. Chem. Soc. 1926, 48 (1),257-262.
Hazard Statements: H302-H331-H315-H318-H350-H335-H373
Harmful if swallowed. Toxic if inhaled. Causes skin irritation. Causes serious eye damage. May cause cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements: P260-P201-P280-P305+P351+P338-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.