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Benzyl chloromethyl ether is employed in the introduction of benzoyloxy- and hydroxymethyl groups.
Dane A. Goff.; Ralph N. HarrisIII.; Jeffrey C. Bottaro.; Clifford D. Bedford. Cleavage of methoxymethyl ethers with boron trichloride. A convenient, versatile preparation of chloromethyl ether derivatives. J. Org. Chem. 1986, 51 (24),4711-4714.
Arthur J. Hill.; DeWitt T. Keach. Some Ether-Substituted Derivatives Of Diethyl Malonate And Barbituric Acid.J. Am. Chem. Soc. 1926, 48 (1),257-262.
Hazard Statements: H227-H302-H312-H315-H319-H332-H334-H335-H350
Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause cancer.
Precautionary Statements: P201-P202-P210-P235-P261-P264b-P270-P271-P280i-P281-P285-P301+P312-P302+P352-P304+P340-P305+P351+P338-P308+P313-P312-P330-P332+P313-P337+P313-P342+P311-P362-P370+P378q-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. If skin irritation occurs: If eye irritation persists: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant