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13265-84-4 - D-Glucal, 97% - (2R,3S,4R)-2-(Hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol - 1,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol - H60239 - Alfa Aesar

H60239 D-Glucal, 97%

CAS Number
13265-84-4
Synonyms
(2R,3S,4R)-2-(Hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol
1,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol

Size Price ($) Quantity Availability
1g 25.70
5g 102.00
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D-Glucal, 97%

MDL
MFCD09039277
EINECS
236-259-3

Chemical Properties

Formula
C6H10O4
Formula Weight
146.14
Melting point
58-60°
Sensitivity
Moisture Sensitive
Solubility
Soluble in Methanol.

Applications

It is an important building block for both solution- and solid-phase synthesis of oligosaccharides.

Notes

Store at 2-8°C. Keep away from oxidizing agents. Moisture sensitive.

Literature References

Edward J. Hehre.; Dorothy S. Genghof.; Himan Sternlicht.; Curtis F. Brewer. Scope and mechanism of carbohydrase action: stereospecific hydration of D-glucal catalyzed by α- and β-glucosidase.Biochemistry. 1977, 16 (9),1780-1787.

William R. Roush.; David P. Sebesta.; Chad E. Bennett. Stereoselective synthesis of 2-deoxy-β-glycosides from glycal precursors. 1. Stereochemistry of the reactions of d-glucal derivatives with phenylsulfenyl chloride and phenylselenenyl chloride. Tetrahedron. 1997, 53 (26),8825-8836.

Other References

Harmonized Tariff Code
2932.99
TSCA
No

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