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It is an important building block for both solution- and solid-phase synthesis of oligosaccharides.
Edward J. Hehre.; Dorothy S. Genghof.; Himan Sternlicht.; Curtis F. Brewer. Scope and mechanism of carbohydrase action: stereospecific hydration of D-glucal catalyzed by α- and β-glucosidase.Biochemistry. 1977, 16 (9),1780-1787.
William R. Roush.; David P. Sebesta.; Chad E. Bennett. Stereoselective synthesis of 2-deoxy-β-glycosides from glycal precursors. 1. Stereochemistry of the reactions of d-glucal derivatives with phenylsulfenyl chloride and phenylselenenyl chloride. Tetrahedron. 1997, 53 (26),8825-8836.