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H60269 Bis[2-(dicyclohexylphosphino)ethyl]amine, 97+%

CAS Number
550373-32-5
Synonyms

Stock No. Size Price ($) Quantity Availability
H60269-MD 250mg 47.00
H60269-03 1g 144.00
H60269-06 5g 590.00
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Bis[2-(dicyclohexylphosphino)ethyl]amine, 97+%

MDL
MFCD17014019

Chemical Properties

Formula
C28H53NP2
Formula Weight
465.67
Melting point
64-69°
Storage & Sensitivity
Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Insoluble in water.

Applications

It is used as a pharmaceutical intermediate.

Notes

Air Sensitive. Incompatible with oxidizing agents.

Literature References

Claudio Bianchini.; Lionel Glendenning.; Maurizio Peruzzini.; Graham Purches.; Fabrizio Zanobini.; Erica Farnetti.; Mauro Graziani.; Giorgio Nardin. Synthesis of the New Chiral (R)- and (S)-Aminodiphosphine Ligands sec-Butylbis(2-(diphenylphosphino)ethyl)amine, sec-Butylbis(2-(dicyclohexylphosphino)ethyl)amine, and (α-Methylbenzyl)bis(2-(dicyclohexylphosphino)ethyl)amine and Their Organometallic Chemistry When Combined with Iridium. Organometallics. 1997, 16 (20),4403-4414.

Pierluigi Barbaro.; Claudio Bianchini.; Antonio Togni. Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)-P3 or -P2S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone.Organometallics. 1997, 16 (13),3004-3014.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

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    Bis[2-(di-tert-butylphosphino)ethyl]amine, 10% w/w soln. in THF
  • H60853

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