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35193-63-6 - 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99% - H60395 - Alfa Aesar

H60395 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%

CAS Number
35193-63-6
Synonyms

Size Price ($) Quantity Availability
1g 17.70
5g 71.90
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1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%

MDL
MFCD00010045
EINECS
252-425-8

Chemical Properties

Formula
C20H13O4P
Formula Weight
348.29
Solubility
Extremely low soluble in water.

Applications

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

Notes

Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.

Literature References

H Nakamura.; A Sano.; H Sumii. Chiral Separation of (R, S)-1, 1'-Binaphthyl-2, 2'-diyl Hydrogenphosphate by Capillary Electrophoresis Using Monosaccharides as Chiral Selectors. Analytical sciences. 199814 (2), 375-378.

Other References

Harmonized Tariff Code
2934.99
TSCA
No

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