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H60466 4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate, 95%

CAS Number
80149-80-0
Synonyms
Carbonic acid 4-nitrophenyl 2-(trimethylsilyl)ethyl ester
Teoc-ONp

Stock No. Size Price ($) Quantity Availability
H60466-03 1g 49.10
H60466-06 5g 195.00
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4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate, 95%

MDL
MFCD00042930
EINECS
279-406-7

Chemical Properties

Formula
C12H17NO5Si
Formula Weight
283.35
Melting point
35-40°
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Light Sensitive. Store under Nitrogen.
Solubility
Slightly soluble in water.

Applications

It is employed as a reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-.

Notes

Moisture & Light Sensitive. Store at 2-8°C.

Literature References

Andre Rosowsky.; Joel E. Wright. N.µ.-Alkoxycarbonylation of .alpha.,.µ.-diamino acids with 2-(trimethylsilyl)ethyl 4-nitrophenyl carbonate. J. Org. Chem. 1983, 48 (9), 1539-1541.

Takamasa Iimori.; Takafumi Shibazaki.; Shiro Ikegami. A novel intramolecular decarboxylative glycosylation via mixed carbonate. Tetrahedron Lett. 1996, 37 (13),2267-2270.

Other References

Beilstein
4320585
Harmonized Tariff Code
2931.90
TSCA
No

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