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131890-26-1 - Bis[2-(diisopropylphosphino)ethyl]amine, 10% w/w soln. in THF - H60468 - Alfa Aesar

H60468 Bis[2-(diisopropylphosphino)ethyl]amine, 10% w/w soln. in THF

CAS Number
131890-26-1
Synonyms

Size Price ($) Quantity Availability
1g 28.50
5g 102.00
25g 395.00
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Bis[2-(diisopropylphosphino)ethyl]amine, 10% w/w soln. in THF

MDL
MFCD17018778

Chemical Properties

Formula
C16H37NP2
Formula Weight
305.42
Density
0.884
Refractive Index
1.4180
Sensitivity
Air Sensitive
Solubility
Immiscible with water.

Applications

Bis[2-(diisopropylphosphino)ethyl]amine acts as ligand and form complexes with ruthenium, which finds application in the dehydrogenation of ethanol.

Notes

Air sensitive. Incompatible with oxidizing agents and oxygen.

Literature References

Sharninghausen, L. S.; Mercado, B. Q.; Crabtree, R. H.; Hazari, N. Selective conversion of glycerol to lactic acid with iron pincer precatalysts. Chem. Commun. 2015, 51 (90), 16201-16204.

Alberico, E.; Nielsen, M. Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol. Chem. Commun. 2015, 51 (31), 6714-6725.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.39
TSCA
No

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