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H60493 Bis[2-(di-tert-butylphosphino)ethyl]amine, 10% w/w soln. in THF

CAS Number
944710-34-3
Synonyms

Stock No. Size Price ($) Quantity Availability
H60493-03 1g 33.30
H60493-06 5g 119.00
H60493-14 25g 457.00
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Bis[2-(di-tert-butylphosphino)ethyl]amine, 10% w/w soln. in THF

MDL
MFCD17014018

Chemical Properties

Formula
C20H45NP2
Formula Weight
361.53
Density
0.911
Refractive Index
1.4180
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Insoluble in water.

Applications

This compound is involved in the transition metal-catalyzed addition of amines to acrylic acid derivatives.

Notes

Air Sensitive. Incompatible with oxidizing agents.

Literature References

Motoi Kawatsura.; John F. Hartwig. Transition Metal-Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines.Organometallics. 2001, 20 (10),1960-1964.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H315-H318-H335-H336-H351

Highly flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P281-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P332+P313-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.39
TSCA
No

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