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92206-72-9 - 4-Bromobenzylmagnesium bromide, 0.25M in diethyl ether - H60905 - Alfa Aesar

H60905 4-Bromobenzylmagnesium bromide, 0.25M in diethyl ether

CAS Number
92206-72-9
Synonyms

Size Price ($) Quantity Availability
100ml 316.00
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4-Bromobenzylmagnesium bromide, 0.25M in diethyl ether

MDL
MFCD01319901

Chemical Properties

Formula
C7H6Br2Mg
Formula Weight
274.24
Boiling Point
34.6°
Flash Point
-45°(-49°F)
Sensitivity
Air & Moisture Sensitive
Solubility
Insoluble in water.

Applications

It is used as a pharmaceutical intermediate.

Notes

Air and moisture sensitive. Incompatible with strong oxidizing agents.

Literature References

Tracey S. Cooper.;Alexander S. Larigo.; Pierre Laurent.; Christopher J. Moody.; Andrew K. Takle. Chiral oxime ethers in asymmetric synthesis. O-(1-Phenylbutyl)benzyloxyacetaldoxime, a versatile reagent for the asymmetric synthesis of protected 1,2-aminoalcohols, α-amino acid derivatives, and 2-hydroxymethyl nitrogen heterocycles including iminosugars. Org. Biomol. Chem. 2005, 3 (7),1252-1262.

Nuha Alharbi.; Alejandro Díaz-Moscoso.; Graham J. Tizzard.; Simon J. Coles.; Michael J. Cook.; Andrew N. Cammidge. Improved syntheses of meso-aryl tetrabenzotriazaporphyrins (TBTAPs). Tetrahedron. 2014, 70 (40),7370-7379.

GHS Hazard and Precautionary Statements

Hazard Statements: H224-H314-H302-H336

Extremely flammable liquid and vapour. Causes severe skin burns and eye damage. Harmful if swallowed. May cause drowsiness or dizziness.

Precautionary Statements: P210-P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
I
Harmonized Tariff Code
2931.90
TSCA
No

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