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H61261 2'-Bromo-5'-fluoroacetophenone, 98%

CAS Number
1006-33-3
Synonyms

Stock No. Size Price ($) Quantity Availability
H61261-MD 250mg 24.80
H61261-03 1g 73.40
H61261-06 5g 292.00
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2'-Bromo-5'-fluoroacetophenone, 98%

MDL
MFCD07780635

Chemical Properties

Formula
C8H6BrFO
Formula Weight
217.04
Boiling Point
144°/18mm
Refractive Index
1.5525
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in methanol.

Applications

2'-Bromo-5'-fluoroacetophenone is used in the synthesis of oxabicyclic compounds. It is also used in the enantioselective synthesis of chiral 3-aryl-1-indanone molecules.

Notes

Light Sensitive. Store in cool, well ventilated area. Keep container tightly closed.

Literature References

Monica Dell'Acqua; Giorgio Abbiati; Antonio Arcadi; and Elisabetta Rossi. Silver-catalysed intramolecular cyclisation of 2-alkynylacetophenones and 3-acetyl-2-alkynylpyridines in the presence of ammonia. Org. Biomol. Chem. 2011, 97836-7848.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2914.79
TSCA
No

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