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459-72-3 - Ethyl fluoroacetate, 98% - Fluoroacetic ethyl ester - H61340 - Alfa Aesar

H61340 Ethyl fluoroacetate, 98%

CAS Number
459-72-3
Synonyms
Fluoroacetic ethyl ester

Size Price ($) Quantity Availability
10g 23.49
50g 56.62
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Ethyl fluoroacetate, 98%

MDL
MFCD00000450
EINECS
207-297-8

Chemical Properties

Formula
C4H7FO2
Formula Weight
106.10
Boiling Point
119-120°
Density
1.093
Refractive Index
1.3750
Solubility
Decomposes in water.

Applications

Ethyl fluoroacetate is used in the synthesis of 4-deoxy-4-fluoro-muscarines. It is also used as starting reagent for the synthesis of ethyl(diethoxyphosphoryl)fluoroacetate. and in development of an ammonolysis-based microencapsulation process.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

John T. Welch.; K. Seper.; S. Eswarakrishnan.; J. Samartino. Preparation of alpha-fluoroenolates and their use in the directed aldol reaction. J. Org. Chem. 1984, 49 (24), 4720-4721.

C. J. Martin.; A. I. Schepartz.; B. F. Daubert. The Preparation of 2-Heptenal and 2-Nonenal. J. Am. Chem. Soc. 1948, 70 (7), 2601-2602.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H330-H226

Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Flammable liquid and vapour.

Precautionary Statements: P210-P260-P301+P310-P303+P361+P353-P304+P340-P320-P330-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,4167
Beilstein
1743761
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
Yes
RTECS
AH7175000

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