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333-27-7 - Methyl trifluoromethanesulfonate, 97% - Trifluoromethanesulfonic acid methyl ester - H61758 - Alfa Aesar

H61758 Methyl trifluoromethanesulfonate, 97%

CAS Number
333-27-7
Synonyms
Trifluoromethanesulfonic acid methyl ester

Size Price ($) Quantity Availability
25g 107.00
100g 334.00
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Methyl trifluoromethanesulfonate, 97%

MDL
MFCD00000409
EINECS
206-371-7

Chemical Properties

Formula
C2H3F3O3S
Formula Weight
164.10
Boiling Point
99°
Flash Point
38°(100°F)
Density
1.500
Refractive Index
1.3260
Sensitivity
Air Sensitive

Applications

Methyl trifluoromethanesulfonate is used as a powerful methylating reagent in chemistry. Further, it is used in the conversion of amines to methyl ammonium triflates. In addition, it is also used in Suzuki reaction.

Notes

Air and moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents, strong bases, strong acids and strong reducing agents. Hydrolyzes with water.

Literature References

Huang, X.; Gillies, R. J.; Tian, H. Synthesis of [18F] 4-amino-N-(3-chloro-4-fluorophenyl)-N'-hydroxy-1, 2, 5-oxadiazole-3-carboximidamide (IDO5L): a novel potential PET probe for imaging of IDO1 expression. J. Labelled Compd. Radiopharm. 2015, 58 (4), 156-162.

Phelan, V. V.; Moree, W. J.; Aguilar, J.; Cornett, D. S.; Koumoutsi, A.; Noble, S. M.; Pogliano, K.; Guerrero, C. A.; Dorrestein, P. C. Impact of a transposon insertion in phzF2 on the specialized metabolite production and interkingdom interactions of Pseudomonas aeruginosa. J. Bacteriol. 2014, 196 (9), 1683-1693.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H314-H318

Flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2905.19
TSCA
Yes

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