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1583-88-6 - 2-(4-Fluorophenyl)ethylamine, 97% - 4-Fluorophenethylamine - H61791 - Alfa Aesar

H61791 2-(4-Fluorophenyl)ethylamine, 97%

CAS Number
1583-88-6
Synonyms
4-Fluorophenethylamine

Size Price ($) Quantity Availability
25g 57.00
100g 190.00
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2-(4-Fluorophenyl)ethylamine, 97%

MDL
MFCD00134208
EINECS
216-435-6

Chemical Properties

Formula
C8H10FN
Formula Weight
139.17
Boiling Point
50-52°
Flash Point
79°(174°F)
Density
1.061
Refractive Index
1.507
Solubility
Slightly soluble in water.

Applications

2-(4-Fluorophenyl)ethylamine may be employed as nucleophile in the synthesis of 2-amino-4-arylpyrimidine derivatives. It is suitable for use in the preparation of ortho-metalated primary phenethylamines having electron-releasing and electron-withdrawing groups on the aromatic ring, leading to complexes containing six membered palladacycles.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents and acids.

Literature References

Mitra Matloobi; C.Oliver Kappe. Microwave-assisted solution- and solid-phase synthesis of 2-amino-4-arylpyrimidine derivatives. Journal of Combinatorial Chemistry. 2007, 9,(2), 275-284.

 

Jose Vicente; Isabel Saura-Llamas; Jesus Cuadrado; Carmen Ramirez de Arellano. Ortho-metalated primary amines. 6.1 The first synthesis of six-membered palladacycles from primary amines containing electron-withdrawing substituents: end of the limiting rules of Cope and Friedrich on cyclopalladation of benzyl-and phenethylamines. Organometallics. 2003, 22,(26), 5513-5517.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H330-H314-H318-H227

Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Precautionary Statements: P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2921.49
TSCA
No

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