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811862-77-8 - Bis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium(0), Pd 12%-14% - H61964 - Alfa Aesar

H61964 Bis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium(0), Pd 12%-14%

CAS Number
811862-77-8
Synonyms

Size Price ($) Quantity Availability
1g 64.60
5g 227.00
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Bis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium(0), Pd 12%-14%

MDL
MFCD07369799

Chemical Properties

Formula
C42H44O10Pd
Formula Weight
815.23
Melting point
170-178°
Solubility
Insoluble in water.

Applications

Bis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium(0) used as catalyst in pharmaceutical research.

Notes

Store in cool, well ventilated area. Keep container tightly closed. Store away from oxidizing agent.

Literature References

Jan Streuff; David E. White; Scott C. Virgil; & Brian M. Stoltz. A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres. Nature Chemistry. 2010, 2 192-196.

Amarajothi Dhakshinamoorthy; Kasi Pitchumani. Clay-anchored non-heme iron-salen complex catalyzed cleavage of Cdouble bond; length as m-dashC bond in aqueous medium. Tetrahedron. 2006, 62(42), 9911-9918.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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