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H61979 5'-Bromo-2'-hydroxyacetophenone, 98%

CAS Number
1450-75-5
Synonyms
2-Acetyl-4-bromophenol

Stock No. Size Price ($) Quantity Availability
H61979-09 10g 37.80
H61979-18 50g 151.00
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5'-Bromo-2'-hydroxyacetophenone, 98%

MDL
MFCD00191850

Chemical Properties

Formula
C8H7BrO2
Formula Weight
215.04
Melting point
56-60°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in Chloroform

Applications

5?-Bromo-2?-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2?-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N?-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

R.A. Nyquist. The O-H out-of-plane deformation in intramolecularly hydrogen bonded phenols. Spectrochimica Acta. 1995, 19, (10), 1655-1664.

Biswanath Das.; Katta Venkateswarlu.; Maddeboina Krishnaiah.; Harish Holla. An efficient, rapid and regioselective nuclear bromination of aromatics and heteroaromatics with NBS using sulfonic-acid-functionalized silica as a heterogeneous recyclable catalyst . Tetrahedron Letters. 2006, 93, (24), 8693-8697.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2914.79
TSCA
No
RTECS
KM5556350

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