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95715-87-0 - (R)-(+)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde, 95% - tert-Butyl (R)-(+)-4-formyl-2,2-dimethyloxazolidine-3-carboxylate - (R)-Garner's Aldehyde - H63351 - Alfa Aesar

H63351 (R)-(+)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde, 95%

CAS Number
95715-87-0
Synonyms
tert-Butyl (R)-(+)-4-formyl-2,2-dimethyloxazolidine-3-carboxylate
(R)-Garner's Aldehyde

Size Price ($) Quantity Availability
250mg 66.30
1g 204.00
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(R)-(+)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde, 95%

MDL
MFCD00674064

Chemical Properties

Formula
C11H19NO4
Formula Weight
229.27
Boiling Point
67°/0.3mm
Flash Point
102°(216°F)
Density
1.06
Refractive Index
1.4450
Sensitivity
Air Sensitive

Applications

(R)-(+)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde is used in the preparation of fluorinated analogs of glutemic and glutamine.

Notes

Incompatible with strong oxidizing agents.

Literature References

de Villiers, J.; de Villiers, M.; Geertsema, E. M.; Raj, H.; Poelarends, G. J. Chemoenzymatic Synthesis of ortho-, meta-, and para-Substituted Derivatives of L-threo-3-Benzyloxyaspartate, An Important Glutamate Transporter Blocker. ChemCatChem 2015, 7 (13), 1931-1934.

Singh, P.; Samanta, K.; Das, S. K.; Panda, G. Amino acid chirons: a tool for asymmetric synthesis of heterocycles. Org. Biomol. Chem. 2014, 12 (33), 6297-6339.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,4371
Beilstein
3651554
Harmonized Tariff Code
2934.99
TSCA
No

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