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60456-23-7 - (S)-(-)-Glycidol, 99+%, ee 99+% - (S)-(-)-Oxirane-2-methanol - (S)-(-)-2,3-Epoxy-1-propanol - H63502 - Alfa Aesar

H63502 (S)-(-)-Glycidol, 99+%, ee 99+%

CAS Number
60456-23-7
Synonyms
(S)-(-)-Oxirane-2-methanol
(S)-(-)-2,3-Epoxy-1-propanol

Size Price ($) Quantity Availability
1g 23.90
5g 84.70
25g 303.00
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(S)-(-)-Glycidol, 99+%, ee 99+%

MDL
MFCD00074874

Chemical Properties

Formula
C3H6O2
Formula Weight
74.08
Boiling Point
66-67°/19mm
Flash Point
66°(151°F)
Density
1.116
Refractive Index
1.4330
Solubility
Soluble in chloroform, DMSO and methanol.

Applications

(S)-(-)-Glycidol is employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis. Also used as a starting reagent to synthesize non-peptidic HIV protease inhibitors.

Notes

Store in freezer at(-20°C). Keep container tightly closed. Store away from oxidizing agent.

Literature References

Neil A Sheddan; Johann Mulzer. Cross metathesis as a general strategy for the synthesis of prostacyclin and prostaglandin analogues. Organic Letters. 2006, 8(14), 3101-3104.

Haines TD; Adlaf KJ; Pierceall RM, et al. Direct Determination of MCPD Fatty Acid Esters and Glycidyl Fatty Acid Esters in Vegetable Oils by LC-TOFMS. J. Am. Oil Chem. Soc. 2011, 88(1), 1-14.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H312-H331-H315-H319-H341-H350-H360-H335

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. Suspected of causing genetic defects. May cause cancer. May damage fertility or the unborn child. May cause respiratory irritation.

Precautionary Statements: P210u-P201-P261-P305+P351+P338-P405-P501a

Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
79783
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2910.90
TSCA
No
RTECS
RR0508100

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