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26137-08-6 - Methyl 3-bromothiophene-2-carboxylate, 97% - 3-Bromothiophene-2-carboxylic acid methyl ester - H63813 - Alfa Aesar

H63813 Methyl 3-bromothiophene-2-carboxylate, 97%

CAS Number
26137-08-6
Synonyms
3-Bromothiophene-2-carboxylic acid methyl ester

Size Price ($) Quantity Availability
250mg 25.00
1g 77.25
5g 309.00
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Methyl 3-bromothiophene-2-carboxylate, 97%

MDL
MFCD00173839

Chemical Properties

Formula
C6H5BrO2S
Formula Weight
221.07
Melting point
50-51°
Solubility
Slightly soluble in water.

Applications

Methyl 3-bromothiophene-2-carboxylate is employed as a intermediate for pharmaceutical and chemical research.

Notes

Store in freezer at(-20°C). Keep container tightly closed. Store away from oxidizing agent.

Literature References

Viktor O. Iaroshenko; Sajid Ali; Tariq Mahmood Babar; Muhammad S.A. Abbasi; Vyacheslav Ya Sosnovskikh; Alexander Villinger; Andrey Tolmacheve; Peter Lange. Efficient synthesis of novel thieno[3,2-b]-, [2,3-c]- and [3,2-c]pyridones by Sonogashira coupling of bromothiophenes with terminal alkynes and subsequent intramolecular C-N bond-forming reaction. Tetrahedron. 2013, 69(15), 3167-3181.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2934.99
TSCA
No

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