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H63813 Methyl 3-bromothiophene-2-carboxylate, 97%

CAS Number
26137-08-6
Synonyms
3-Bromothiophene-2-carboxylic acid methyl ester

Stock No. Size Price ($) Quantity Availability
H63813-MD 250mg 24.20
H63813-03 1g 71.80
H63813-06 5g 286.00
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Methyl 3-bromothiophene-2-carboxylate, 97%

MDL
MFCD00173839

Chemical Properties

Formula
C6H5BrO2S
Formula Weight
221.07
Melting point
50-51°
Storage & Sensitivity
Store at -20°C.
Solubility
Slightly soluble in water.

Applications

Methyl 3-bromothiophene-2-carboxylate is employed as a intermediate for pharmaceutical and chemical research.

Notes

Store in freezer at(-20°C). Keep container tightly closed. Store away from oxidizing agent.

Literature References

Viktor O. Iaroshenko; Sajid Ali; Tariq Mahmood Babar; Muhammad S.A. Abbasi; Vyacheslav Ya Sosnovskikh; Alexander Villinger; Andrey Tolmacheve; Peter Lange. Efficient synthesis of novel thieno[3,2-b]-, [2,3-c]- and [3,2-c]pyridones by Sonogashira coupling of bromothiophenes with terminal alkynes and subsequent intramolecular C-N bond-forming reaction. Tetrahedron. 2013, 69(15), 3167-3181.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2934.99
TSCA
No

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