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H63867 2-Bromopyridine-5-carboxaldehyde, 95%

CAS Number
149806-06-4
Synonyms
6-Bromonicotinaldehyde

Stock No. Size Price ($) Quantity Availability
H63867-03 1g 22.00
H63867-06 5g 86.30
H63867-14 25g 359.00
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2-Bromopyridine-5-carboxaldehyde, 95%

MDL
MFCD04115419

Chemical Properties

Formula
C6H4BrNO
Formula Weight
186.01
Melting point
104-110° dec
Storage & Sensitivity
Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in dichloromethane, ether, ethyl acetate and methanol.

Applications

A useful synthetic intermediate. 6-Bromonicotinaldehyde is used in wittig reaction. Hydrodehalogenation of 6-bromonicotinaldehyde to produce alcohol.

Notes

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air. 2-7°C Refrigerate.

Literature References

Xi-Bo Chen,; Qiu-Peng Hu,; Qian-Jia Yuan,; Wei Ding,; Jiangmeng Ren,; Bu-Bing Zeng. Simultaneous dehalogenation and hydrogenation reduction of halogen-heteroaromatic aldehydes. Tetrahedron Letters. 2012, 53(53), 3798-3801.

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GHS Hazard and Precautionary Statements

Hazard Statements: H315-H317-H319-H335

Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P272-P280-P302+P352-P304+P340-P305+P351+P338-P312-P333+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2933.39
TSCA
No

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