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H64026 4-Bromo-2-methoxypyridine, 98%

CAS Number

Stock No. Size Price ($) Quantity Availability
H64026-03 1g 38.40
H64026-06 5g 140.00
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4-Bromo-2-methoxypyridine, 98%


Chemical Properties

Formula Weight
Melting point
Boiling Point
Storage & Sensitivity
Keep Cold.
Slightly soluble in water.


4-Bromo-2-methoxypyridine used in the synhesis of Imidazo [1, 2-a] pyrimidines. Suzuki coupling between 4-methoxyphenylboronic acid and 4-bromo-2-methoxypyridine affords 1, 5-disubstituted pyridones. Starting material used in a synthesis of crown-ester-bipyridines and viologens via sodium or nickel reductive coupling, side chain oxidation and esterification.


Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heat.

Literature References

F. Trecourt, M. Mallet, F. Marsais, G. Queguiner.Catalyzed metalation applied to 2-methoxypyridine . J. Org. Chem. 1988, 53 (7), 1367-1371.

Wesley P. Blackaby,; John R. Atack,; Frances Bromidge,; José L. Castro,; Simon C. Goodacre,; David J. Hallett. Imidazo[1,2-a]pyrimidines as functionally selective GABAA ligands. Bioorganic & Medicinal Chemistry Letters. 2005, 16 (5), 1175-1179.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code


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  • 43290

    Cobalt wire, 2.0mm (0.08in) dia, 99.95% (metals basis)
  • L11005

    2-Bromoethyl phenyl sulfide, 97%
  • B22928

    trans-1,2-Diaminocyclohexane-N,N,N',N'-tetraacetic acid monohydrate, 98%
  • 31558

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