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89878-14-8 - Diethyl(3-pyridyl)borane, 98% - 3-(Diethylboryl)pyridine - H64225 - Alfa Aesar

H64225 Diethyl(3-pyridyl)borane, 98%

CAS Number
89878-14-8
Synonyms
3-(Diethylboryl)pyridine

Size Price ($) Quantity Availability
5g 34.10
25g 136.00
100g 546.00
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Diethyl(3-pyridyl)borane, 98%

MDL
MFCD00012348

Chemical Properties

Formula
C9H14BN
Formula Weight
147.03
Melting point
172-175° lit.
Solubility
Slightly soluble in water.

Applications

Reactant for: preparation of inhibitors of ataxia telangiectasia mutated and Rad3 related (ATR) protein kinase as potential anticancer agents, N-Methylation reactions of the pyridyl group, Palladium catalyzed amination reactions, intramolecular Heck reactions, Coupling reactions and Synthesis of trisubstituted pyrimidines from polyhalopyrimidines via Suzuki coupling.

Notes

Store in cool, dry place in tightly closed container. With adequate ventilation. Store away from oxidizing agent.

Literature References

Minoru Ishikura; Tsukasa Ohta; Masanao Terashima. A Novel Synthesis of 4-Aryl-and 4-Heteroarylpyridines via Diethyl (4-pyridyl) borane. Chemical and Pharmaceutical Bulletin.1985 33(11), 4755-4763.

Antonio Guarna; Ernesto G. Occhiato; Fabrizio Machetti; and Vittoria Giacomellia.19-Nor-10-azasteroids. 5.1 A Synthetic Strategy for the Preparation of (+)-17-(3-Pyridyl)-(5β)-10-azaestra-1,16- dien-3-one, a Novel Potential Inhibitor for Human Cytochrome P45017α (17α-Hydroxylase/C17,20-lyase). J. Org. Chem. 1999 64(13),4985-4989.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
4381494
Harmonized Tariff Code
2933.39
TSCA
No

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