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29681-42-3 - Methyl 4-bromopyridine-2-carboxylate, 97+% - 4-Bromopyridine-2-carboxylic acid methyl ester - Methyl 4-bromopicolinate - H64327 - Alfa Aesar

H64327 Methyl 4-bromopyridine-2-carboxylate, 97+%

CAS Number
29681-42-3
Synonyms
4-Bromopyridine-2-carboxylic acid methyl ester
Methyl 4-bromopicolinate

Size Price ($) Quantity Availability
1g 24.80
5g 130.81
25g 428.80
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Methyl 4-bromopyridine-2-carboxylate, 97+%

MDL
MFCD07374897

Chemical Properties

Formula
C7H6BrNO2
Formula Weight
216.03
Melting point
54-56°
Solubility
Slightly soluble in water.

Applications

It finds its application as a useful synthetic intermediate and in the straightforward and efficient synthesis of 3-benzyloxy-4-bromopicolinate ester and 3-benzyloxy-5-bromopicolinate ester, common building blocks for pharmaceuticals and agrochemicals. It is used in the synthesis of biaryl mannoside FimH inhibitors for use in urinary infection treatment.

Notes

Store away from heat and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep it refrigerated.

Literature References

Tristan Verdelet, et al. Straightforward and efficient synthesis of 3-benzyloxy-4-bromopicolinate ester and 3-benzyloxy-5-bromopicolinate ester, common building blocks for pharmaceuticals and agrochemicals.Tetrahedron.,2011,67(45), 8757-8762.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
473047
Harmonized Tariff Code
2933.39
TSCA
No

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