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19500-95-9 - Methoxyacetic anhydride, 95% - Intermediate of 5-Aza-2'-deoxycytidine - H64541 - Alfa Aesar

H64541 Methoxyacetic anhydride, 95%

CAS Number
19500-95-9
Synonyms
Intermediate of 5-Aza-2'-deoxycytidine

Size Price ($) Quantity Availability
25g 76.50
100g 245.00
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Methoxyacetic anhydride, 95%

MDL
MFCD11976032
EINECS
243-114-8

Chemical Properties

Formula
C6H10O5
Formula Weight
162.14
Sensitivity
Moisture Sensitive
Solubility
Very Soluble in water.(193 g/L) (25°C)

Applications

Methoxyacetic anhydride is used as the intermediate of 5-Aza-2'-deoxycytidine.

Notes

Moisture sensitive. Store in cool dry place. Keep container tightly closed. Incompatible with oxidizing agents.

Literature References

Isamu Shiina.; Mari Kubota.; Hiromi Oshiumi.; Minako Hashizume. An Effective Use of Benzoic Anhydride and Its Derivatives for the Synthesis of Carboxylic Esters and Lactones:? A Powerful and Convenient Mixed Anhydride Method Promoted by Basic Catalysts.J. Org. Chem. 2004, 69 (6),1822-1830 .

S. E. Vles. The determination of the velocity of hydrolysis of acid anhydrides by the aniline-water method. Recueil des Travaux Chimiques des Pays-Bas. 1933, 52 (10),809-826 .

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1771552
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2918.99
TSCA
No

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