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H64950 Copper(I) thiophene-2-carboxylate

CAS Number
68986-76-5
Synonyms

Stock No. Size Price ($) Quantity Availability
H64950-03 1g 65.60
H64950-06 5g 264.00
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Copper(I) thiophene-2-carboxylate

MDL
MFCD02183524

Chemical Properties

Formula
C5H3CuO2S
Formula Weight
190.68
Storage & Sensitivity
Air Sensitive. Light Sensitive. Store under Nitrogen. Ambient temperatures.

Applications

Reactant or reagent used for studies of xenobiotic response safener derivatives, synthesis of functionalized BODIPY dye analogs, orthogonal cross-coupling reactions, preparation of parent borondipyrromethene system and Copper mediated cross-coupling.

Notes

Air and Light Sensitive. Protect from light store in dark. Store away from air. Keep container tightly closed. Store away from oxidizing agent.

Literature References

Zhihui Zhang; Ying Yu; Lanny S Liebeskind. N-amidation by copper-mediated cross-coupling of organostannanes or boronic acids with o-acetyl hydroxamic acids. Organic Letters.2011 10(14), 3005-3008.

Ismael J Arroyo; Rongrong Hu; Gabriel Merino; Ben Zhong Tang; Eduardo Peña-Cabrera.The smallest and one of the brightest. Efficient preparation and optical description of the parent borondipyrromethene system. Journal of Organic Chemistry.2009 74(15), 5719-5722.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H318-H335

Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2934.99
TSCA
No

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