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68986-76-5 - Copper(I) thiophene-2-carboxylate - H64950 - Alfa Aesar

H64950 Copper(I) thiophene-2-carboxylate

CAS Number
68986-76-5
Synonyms

Size Price ($) Quantity Availability
1g 63.20
5g 258.00
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Copper(I) thiophene-2-carboxylate

MDL
MFCD02183524

Chemical Properties

Formula
C5H3CuO2S
Formula Weight
190.68
Sensitivity
Air & Light Sensitive

Applications

Reactant or reagent used for studies of xenobiotic response safener derivatives, synthesis of functionalized BODIPY dye analogs, orthogonal cross-coupling reactions, preparation of parent borondipyrromethene system and Copper mediated cross-coupling.

Notes

Air and Light Sensitive. Protect from light store in dark. Store away from air. Keep container tightly closed. Store away from oxidizing agent.

Literature References

Zhihui Zhang; Ying Yu; Lanny S Liebeskind. N-amidation by copper-mediated cross-coupling of organostannanes or boronic acids with o-acetyl hydroxamic acids. Organic Letters.2011 10(14), 3005-3008.

Ismael J Arroyo; Rongrong Hu; Gabriel Merino; Ben Zhong Tang; Eduardo Peña-Cabrera.The smallest and one of the brightest. Efficient preparation and optical description of the parent borondipyrromethene system. Journal of Organic Chemistry.2009 74(15), 5719-5722.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2934.99
TSCA
No

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