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41011-01-2 - 2-Bromo-3'-chloroacetophenone, 97% - 3-Chlorophenacyl bromide - H66077 - Alfa Aesar

H66077 2-Bromo-3'-chloroacetophenone, 97%

CAS Number
41011-01-2
Synonyms
3-Chlorophenacyl bromide

Size Price ($) Quantity Availability
1g 20.60
5g 72.60
25g 290.00
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2-Bromo-3'-chloroacetophenone, 97%

MDL
MFCD00792669

Chemical Properties

Formula
C8H6BrClO
Formula Weight
233.49
Melting point
39-43°
Boiling Point
122-124°
Flash Point
>110°(230°F)

Applications

2-Bromo-3'-chloroacetophenone acts as a Substrate used in a one-step preparation of symmetrical 1,4-diketones in the presence of Zn-I2.

Notes

Store at 4°C. Incompatible with oxidizing agents.

Literature References

Claudio Giordano; Graziano Castaldi; Francesco Casagrande and Aldo Belli. Esters of α-arylalkanoic acids from ‘masked’α-halogenoalkyl aryl ketones and silver salts: synthetic, kinetic, and mechanistic aspects. J. Chem. Soc., Perkin Trans. 1.1982, 2575-2581.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2086002
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2914.79
TSCA
No

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