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631-57-2 - Pyruvonitrile, tech. 90% - 2-Oxopropionitrile - Acetyl cyanide - H66636 - Alfa Aesar

H66636 Pyruvonitrile, tech. 90%

CAS Number
631-57-2
Synonyms
2-Oxopropionitrile
Acetyl cyanide

Size Price ($) Quantity Availability
1g 22.90
5g 91.80
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Pyruvonitrile, tech. 90%

MDL
MFCD00001838
EINECS
211-159-2

Chemical Properties

Formula
C3H3NO
Formula Weight
69.06
Boiling Point
92-93°
Flash Point
14°(57°F)
Density
0.974
Refractive Index
1.3755
Solubility
Soluble in ether and acetonitrile.

Applications

Pyruvonitrile was used in the synthesis of cuprate-carbonyl π-complexes by reaction with Me2CuLi in THF.

Notes

Refrigerate. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Steven H Bertz; Richard A Hardin; Michael D Murphy; Craig A Ogle. π-Complexes from acyl cyanides and lithium dimethylcuprate(I). Chemical Communications. 2013, 49 (29), 3010-3012.

M P Bernstein; S A Sandford; L J Allamandola. The infrared spectra of nitriles and related compounds frozen in Ar and H2O. Astrophysical Journal., 1997, 476 (2), 932-942.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H300-H330-H315-H335-H411-H401

Highly flammable liquid and vapour. Fatal if swallowed. Fatal if inhaled. Causes skin irritation. May cause respiratory irritation. Toxic to aquatic life with long lasting effects. Toxic to aquatic life.

Precautionary Statements: P210-P260-P284-P301+P310-P303+P361+P353-P304+P340-P320-P330-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1737633
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2926.90
TSCA
No

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