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H66636 Pyruvonitrile, tech. 90%

CAS Number
631-57-2
Synonyms
2-Oxopropionitrile
Acetyl cyanide

Stock No. Size Price ($) Quantity Availability
H66636-03 1g 24.80
H66636-06 5g 106.00
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Pyruvonitrile, tech. 90%

MDL
MFCD00001838
EINECS
211-159-2

Chemical Properties

Formula
C3H3NO
Formula Weight
69.06
Boiling Point
92-93°
Flash Point
14°(57°F)
Density
0.974
Refractive Index
1.3755
Storage & Sensitivity
Keep Cold.
Solubility
Soluble in ether and acetonitrile.

Applications

Pyruvonitrile was used in the synthesis of cuprate-carbonyl π-complexes by reaction with Me2CuLi in THF.

Notes

Refrigerate. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Steven H Bertz; Richard A Hardin; Michael D Murphy; Craig A Ogle. π-Complexes from acyl cyanides and lithium dimethylcuprate(I). Chemical Communications. 2013, 49 (29), 3010-3012.

M P Bernstein; S A Sandford; L J Allamandola. The infrared spectra of nitriles and related compounds frozen in Ar and H2O. Astrophysical Journal., 1997, 476 (2), 932-942.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301-H315-H319-H330-H335

Highly flammable liquid and vapour. Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. Fatal if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P284-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1737633
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2926.90
TSCA
No

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