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Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.
Maaike M Appeldoorn; Pieter de Waard; Mirjam A Kabel; Harry Gruppen; Henk A Schols. Enzyme resistant feruloylated xylooligomer analogues from thermochemically treated corn fiber contain large side chains, ethyl glycosides and novel sites of acetylation. Carbohydrate Research. 2013, 381 33-42.
Kawase Y , et al. One-pot synthesis of alkoxyamine derivatives by reductive alkoxyamination with a 2-picoline-borane complex. Heterocycles., 2009, 78 (2), 463-70.
Hazard Statements: H261-H315-H319-H335
In contact with water releases flammable gas. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P223-P231+P232-P261-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Avoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.