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H66696 (R)-(+)-1-(1-Naphthyl)ethylamine, 97%

CAS Number
3886-70-2
Synonyms

Stock No. Size Price ($) Quantity Availability
H66696-06 5g 18.40
H66696-14 25g 78.90
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(R)-(+)-1-(1-Naphthyl)ethylamine, 97%

MDL
MFCD00064114
EINECS
223-425-5

Chemical Properties

Formula
C12H13N
Formula Weight
171.24
Boiling Point
152-153°/11mm
Flash Point
>110°(230°F)
Density
1.060
Refractive Index
1.6230
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Nitrogen.
Solubility
Soluble in water (<10/l).

Applications

It is used in chiral synthesis in organic reactions including the synthesis of β-amino acids and the enantioselective of ketones to nitroolefins. Also used as absolute configuration of primary amines determined using chiral (2-nitrophenyl)proline amides and H NMR.

Notes

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Hee Choon Ahn; Kihang Choi. N-(2-Nitrophenyl)proline: an intramolecular hydrogen bond forming reagent for the determination of the absolute configuration of primary amines.Organic Letters.,2007, 9(19), 3853-3855.

Svetlana B. Tsogoeva; and Shengwei Wei. Highly enantioselective addition of ketones to nitroolefins catalyzed by new thiourea-amine bifunctional organocatalysts. Chem. Commun., 2006, (13),1451-1453.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H314-H335

Toxic if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2208025
Harmonized Tariff Code
2921.49
TSCA
Yes

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