Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

3886-70-2 - (R)-(+)-1-(1-Naphthyl)ethylamine, 97% - H66696 - Alfa Aesar

H66696 (R)-(+)-1-(1-Naphthyl)ethylamine, 97%

CAS Number
3886-70-2
Synonyms

Size Price ($) Quantity Availability
5g 17.50
25g 76.90
Add to Cart Add to Quote Request View Item

(R)-(+)-1-(1-Naphthyl)ethylamine, 97%

MDL
MFCD00064114
EINECS
223-425-5

Chemical Properties

Formula
C12H13N
Formula Weight
171.24
Boiling Point
152-153°/11mm
Flash Point
>110°(230°F)
Density
1.060
Refractive Index
1.6230
Sensitivity
Air Sensitive
Solubility
Soluble in water (<10/l).

Applications

It is used in chiral synthesis in organic reactions including the synthesis of β-amino acids and the enantioselective of ketones to nitroolefins. Also used as absolute configuration of primary amines determined using chiral (2-nitrophenyl)proline amides and H NMR.

Notes

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Hee Choon Ahn; Kihang Choi. N-(2-Nitrophenyl)proline: an intramolecular hydrogen bond forming reagent for the determination of the absolute configuration of primary amines.Organic Letters.,2007, 9(19), 3853-3855.

Svetlana B. Tsogoeva; and Shengwei Wei. Highly enantioselective addition of ketones to nitroolefins catalyzed by new thiourea-amine bifunctional organocatalysts. Chem. Commun., 2006, (13),1451-1453.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312-H314-H318

Toxic if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2208025
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2921.49
TSCA
Yes

Recommended

  • A15691

    Ethyl vinyl ether, 99%, stab.
  • L14102

    (S)-(+)-1-Amino-2-propanol, 98%
  • L19404

    (S)-(+)-2-Amino-1-phenylethanol, 97%
  • H64553

    3-[3-(Trifluoromethyl)phenyl]propanol, 98%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware