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2'-Deoxycytidine-5'-monophosphate is used as a substrate of uridine monophosphate (UMP)/cytidine monophosphate (CMP) kinase (EC 184.108.40.206) to form dCDP which upon phosphorylation to dCTP supports DNA and RNA biosynthesis.
Richard L. Momparler. Pharmacology of 5-Aza-2?-deoxycytidine (decitabine). Seminars in Hematology. 2005, 42, (2), S9-S16.
Lu Liu.; Daniel V. Santi. Exclusion of 2'-deoxycytidine 5'-monophosphate by asparagine 229 of thymidylate synthase. Biochemistry. 1993, 32, (36), 9263-9267.