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14131-84-1 - 2,3:5,6-Di-O-isopropylidene-alpha-D-mannofuranose, 98% - Diacetone-D-mannose - J66303 - Alfa Aesar

J66303 2,3:5,6-Di-O-isopropylidene-alpha-D-mannofuranose, 98%

CAS Number
14131-84-1
Synonyms
Diacetone-D-mannose

Size Price ($) Quantity Availability
5g 55.20
10g 99.00
25g 220.00
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2,3:5,6-Di-O-isopropylidene-alpha-D-mannofuranose, 98%

MDL
MFCD00134206

Chemical Properties

Formula
C12H20O6
Formula Weight
260.28
Form
Powder
Melting point
125-126° dec.
Sensitivity
Hygroscopic
Solubility
Soluble in acetone, methanol, water.

Applications

2,3:5,6-Di-O-isopropylidene-alpha-D-mannofuranose is used in the syntheses of ovalicin1 and of the sugar core of hikizimycin.

Notes

Hygroscopic. Protect from heat. Store under dry inert gas. Incompatible with moisture and oxidizing agents.

Literature References

Shunya Takahashi; Nobuyuki Hishinuma; Hiroyuki Koshino; Tadashi Nakata. Synthesis of ovalicin starting from D-mannose. Journal of Organic Chemistry. 2005, 70, (4), 10162-10165.

GHS Hazard and Precautionary Statements

Precautionary Statements: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
84382
Harmonized Tariff Code
2940.00
TSCA
No

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