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15186-48-8 - 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane - 2,2-(R)-Dimethyl-1,3-dioxolane-4-carboxaldehyde - J66337 - Alfa Aesar

J66337 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane

CAS Number
15186-48-8
Synonyms
2,2-(R)-Dimethyl-1,3-dioxolane-4-carboxaldehyde

Size Price ($) Quantity Availability
1g 53.55
5g 105.06
10g 200.85
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2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane

MDL
MFCD00269682

Chemical Properties

Formula
C6H10O3
Formula Weight
130.14
Form
Liquid
Flash Point
62°(144°F)
Refractive Index
1.454
Solubility
Difficult to mix.

Applications

Reactant involved in organic reactions including, Henry condensation reactions, Synthesis of highly functionalized chiral aziridines, Olefination of aldehydes, C-H oxidations, Aldol-type condensations, Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Steinar Hagen.; Thorleif Anthonsen.; Lars Kilaas. Addition of diazomethane and sulfur ylides to the oxo-group in derivatives of ketoses and aldoses : I. Reactions of 2,3-O-isopropylidene-D-glyceraldehyde. Tetrahedron. 1979, 35, (21), 2583-2589.

Brigitte Hafele.; Volker Jager. A Short Synthesis of (S)-5-Hydroxy-2-penten-4-olide from D-Mannitol via 2,3-O-Isopropylidene-D-glyceraldehyde. Liebigs Annalen der Chemie. 1987, 1987, (1), 85-87.

GHS Hazard and Precautionary Statements

Hazard Statements: H351-H227

Suspected of causing cancer. Combustible liquid.

Precautionary Statements: P210-P201-P280-P281-P202-P308+P313-P370+P378a-P405-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understood. IF exposed or concerned: Get medical advice/attention. In case of fire: Use for extinction: CO2, powder or water spray. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2932.99
TSCA
No

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