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J66871 2,3-O-Isopropylidene-D-erythronolactone, 98%

CAS Number
25581-41-3
Synonyms

Stock No. Size Price ($) Quantity Availability
J66871-03 1g 63.60
J66871-06 5g 222.00
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2,3-O-Isopropylidene-D-erythronolactone, 98%

MDL
MFCD00134440

Chemical Properties

Formula
C7H10O4
Formula Weight
158.15
Form
Powder
Melting point
67-69°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water

Applications

It undergoes Aldol condensations with silyl ketene acetals.1 Employed in spiroannulated carbohydrate synthesis.2 Convergent syntheses of a hydroxylated indolizidine,3 carbohydrate substituted benzoquinones,4 and of the oxazole segment of calyculin5 have been accomplished using this chiral synthon.

Notes

Store at room temperature. Incompatible with heat, oxidizing agents.

Literature References

Jason L. McCartney.; Christopher T. Meta.; Robert M. Cicchillo.; Matthew D. Bernardina.; Timothy R. Wagner.; Peter Norris. Addition of Lithiated C-Nucleophiles to 2,3-O-Isopropylidene-d-erythronolactone:? Stereoselective Formation of a Furanose C-Disaccharide.J. Org. Chem. 2003, 68 (26),10152-10155 .

Other References

Beilstein
1282952
Harmonized Tariff Code
2932.99
TSCA
No

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