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1137-96-8 - N,alpha-Diphenyl nitrone, 97% - L00185 - Alfa Aesar

L00185 N,alpha-Diphenyl nitrone, 97%

CAS Number
1137-96-8
Synonyms

Size Price ($) Quantity Availability
1g 31.60
5g 91.20
25g 342.00
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N,alpha-Diphenyl nitrone, 97%

MDL
MFCD00013895
EINECS
214-509-2

Chemical Properties

Formula
C13H11NO
Formula Weight
197.24
Melting point
113-114°
Solubility
Soluble in water at 25°C, 1120 mg/L.

Applications

It is used as a pharmaceutical intermediate.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Sakura, M, et al. Reaction of cyclohexa-1,2,3-triene with n, alpha -diphenyl-nitrone : formation of seven-membered cyclic amines via piradone derivatives.Heterocycles.,1999,51,(3), 547-556.

For an example of 1,3-dipolar cycloaddition with an alkene to give an isoxazolidine, see: Org. Synth. Coll., 5, 1124 (1973):

Similarly, regioselective addition to propiolic esters or alkynyl ketones gives isoxazolines: Tetrahedron, 44, 1247 (1988). The regioselectivity of 1,3-dipolar additions of nitrones with electron-deficient alkenes has been studied: J. Org. Chem., 49, 276 (1984).

Reviews: 1,3-Dipolar cycloadditions of nitrones: Synthesis, 205 (1975); The [3+2] nitrone-olefin cycloaddition reaction: Org. React., 36, 1 (1988); Synthetic applications of nitrones: Org. Prep. Proced. Int., 17, 25 (1985).

Other References

Beilstein
608470
Harmonized Tariff Code
2929.90
TSCA
No

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