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L00221 1-(Heptafluorobutyryl)imidazole, 98%

CAS Number
32477-35-3
Synonyms

Stock No. Size Price ($) Quantity Availability
L00221-06 5g 110.00
L00221-14 25g 416.00
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1-(Heptafluorobutyryl)imidazole, 98%

MDL
MFCD00014503
EINECS
251-063-8

Chemical Properties

Formula
C7H3F7N2O
Formula Weight
264.10
Melting point
10-13°
Boiling Point
160-162°
Flash Point
77°(170°F)
Density
1.490
Refractive Index
1.3850
Storage & Sensitivity
Store at -20°C. Moisture Sensitive. Store under Argon.
Solubility
Miscible with chloroform and methanol.

Applications

1-(Heptafluorobutyryl)imidazole is used in gas chromatography for the determination of various pharmaceutical compounds like retronecine in biological matrixes. It acts as a reagent for derivatize amine-groups. It plays an essential role to reduce GC column degradation due to its non-acidic property. It is an acylating agent, which converts thermally unstable compounds to its more volatile derivative and then made suitable for GC analysis.

Notes

Hygroscopic and air sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

GC derivatization reagent for amino and hydroxyl groups: Anal. Lett., 1, 311 (1968); 2, 81 (1969); compare Heptafluorobutyric anhydride, A10744.

Zhou, H.; Jin, Q.; Wang, X.; Xu, X. Direct measurement of 3-chloropropane-1,2-diol fatty acid esters in oils and fats by HPLC method. Food Control 2014, 36 (1), 111-118.

Nie, Z.; Zhang, Y.; Chen, J.; Lin, Y.; Wu, B.; Dong, Y.; Feng, J.; Liu, Q.; Xie, J. Monitoring urinary metabolites resulting from sulfur mustard exposure in rabbits, using highly sensitive isotope-dilution gas chromatography-mass spectrometry Anal. Bioanal. Chem. 2014, 406 (21), 5203-5212.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
4488026
Harmonized Tariff Code
2933.29
TSCA
No

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