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L00262 4-(1-Cyclopenten-1-yl)morpholine, 96%

CAS Number
936-52-7
Synonyms
1-(4-Morpholino)cyclopentene
1-(4-Morpholinyl)cyclopentene

Stock No. Size Price ($) Quantity Availability
L00262-14 25g 38.00
L00262-22 100g 117.00
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4-(1-Cyclopenten-1-yl)morpholine, 96%

MDL
MFCD00006162
EINECS
213-316-0

Chemical Properties

Formula
C9H15NO
Formula Weight
153.23
Boiling Point
105-106°/12mm
Flash Point
64°(147°F)
Density
0.957
Refractive Index
1.5118
Storage & Sensitivity
Keep Cold.

Literature References

Useful synthetic intermediate by reaction at the 2-position with various electrophiles. Reviews: Applications of enamines in organic synthesis: Synthesis, 510 (1970). Synthesis of carbonyl compounds from enamines by alkylation, acylation or addition to Michael acceptors: Synthesis, 517 (1983). Advances in enamine chemistry: Tetrahedron, 38, 1975, 3363 (1982). For an example of C-acylation using an acid chloride in the presence of triethylamine, see: Org. Synth. Coll., 5, 533 (1973).

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
117154
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2934.99
TSCA
Yes
RTECS
QE0685000

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