Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

5187-82-6 - (Ethoxycarbonylmethyl)dimethylsulfonium bromide, 98% - (Carboethoxymethyl)dimethylsulfonium bromide - L00266 - Alfa Aesar

L00266 (Ethoxycarbonylmethyl)dimethylsulfonium bromide, 98%

CAS Number
5187-82-6
Synonyms
(Carboethoxymethyl)dimethylsulfonium bromide

Size Price ($) Quantity Availability
10g 47.50
50g 147.00
Add to Cart Add to Quote Request View Item

(Ethoxycarbonylmethyl)dimethylsulfonium bromide, 98%

MDL
MFCD00830557
EINECS
225-968-3

Chemical Properties

Formula
C6H13BrO2S
Formula Weight
229.14
Melting point
ca 80° dec.

Literature References

The derived ylide does not add to carbonyl compounds, although it does undergo 1,4-addition to enones, with formation of cyclopropanecarboxylic esters: Tetrahedron, 23, 545, (1967); J. Org. Chem., 34, 1240 (1969).

/n

Review of the chemistry of sulfonium ylides: Russ. Chem. Rev., 50, 481 (1981).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
4161472
Harmonized Tariff Code
2930.90
TSCA
No
RTECS
WR7600000

Recommended

  • A11410

    (Acetylmethylene)triphenylphosphorane, 99%
  • A12470

    2-Vinylnaphthalene, 97%
  • A13068

    Cyclobutanone, 98%, stab. with ca 0.01% BHT
  • A13298

    Tri-n-butyltin hydride, 97%, stab, with 250-1000ppm BHT
  • A15435

    2-Cyclohexen-1-one, 97%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware