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L00280 Di-tert-butyl hydrazodicarboxylate, 98+%

CAS Number
16466-61-8
Synonyms
N,N'-Di-tert-butoxycarbonylhydrazine
Di-tert-butyl hydrazodiformate

Stock No. Size Price ($) Quantity Availability
L00280-06 5g 51.90
L00280-14 25g 201.00
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Di-tert-butyl hydrazodicarboxylate, 98+%

MDL
MFCD00015000
EINECS
240-512-3

Chemical Properties

Formula
C10H20N2O4
Formula Weight
232.28
Melting point
123-126°
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Di-tert-butyl hydrazodicarboxylate, is used as starting reagent during the four-step synthesis of the aminobicyclopyrazolone hydrochloride. It was used as reagent during Pd-catalyzed amination reactions of halo-pyridine substrates.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Paul Dowd.; Hermann Irngartinger. Tricyclo[2.1.0.02,5]pentane and its derivatives. Chem. Rev. 1989, 89, (5), 985-996.

Paul. Dowd.; Wonghil. Chang.; Yi Hyon. Paik. Tetramethyleneethane, a ground-state triplet. J. Am. Chem. Soc. 1986, 108, (23), 7416-7417.

Effective catalyst, in combination with CuCl : phenanthroline, for the aerobic oxidation of a variety of alcohols, aliphatic primary or secondary, benzylic or allylic to aldehydes or ketones. The method has potential as an ecologically benign process, since water is the only by-product: J. Org. Chem., 64, 2433 (1999):

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1794023
Harmonized Tariff Code
2927.00
TSCA
No

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