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1864-94-4 - Phenyl formate, 95% - Formic acid phenyl ester - L00289 - Alfa Aesar

L00289 Phenyl formate, 95%

CAS Number
1864-94-4
Synonyms
Formic acid phenyl ester

Size Price ($) Quantity Availability
5g 44.91
25g 157.59
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Phenyl formate, 95%

MDL
MFCD00014126
EINECS
217-471-5

Chemical Properties

Formula
HCOOC6H5
Formula Weight
122.12
Boiling Point
72-74°/13mm
Flash Point
71°(159°F)
Density
1.090
Refractive Index
1.5120
Solubility
Immiscible with water, alcohol, ether and benzene.

Applications

Phenyl formate is widely used in the palladium-catalyzed carbonylation of aryl, alkenyl and allyl halides. It is also used as a reagent for the formylation of amines.

Notes

Literature References

Reagent for the formylation of amines in high yield: J. Org. Chem., 36, 3238 (1971).

Ren, W.; Chang, W.; Wang, Y.; Li, J.; Shi, Y. Pd-Catalyzed Regiodivergent Hydroesterification of Aryl Olefins with Phenyl Formate. Org. Lett. 2015, 17 (14), 3544-3547.

Konishi, H.; Nagase, H.; Manabe, K. Concise synthesis of cyclic carbonyl compounds from haloarenes using phenyl formate as the carbonyl source. Chem. Commun. 2015, 51 (10), 1854-1857.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
507113
Harmonized Tariff Code
2915.13
TSCA
No

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