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830-03-5 - 4-Nitrophenyl acetate, 98+% - Acetic acid 4-nitrophenyl ester - L00314 - Alfa Aesar

L00314 4-Nitrophenyl acetate, 98+%

CAS Number
830-03-5
Synonyms
Acetic acid 4-nitrophenyl ester

Size Price ($) Quantity Availability
10g 23.40
50g 58.50
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4-Nitrophenyl acetate, 98+%

MDL
MFCD00007326
EINECS
212-593-5

Chemical Properties

Formula
C8H7NO4
Formula Weight
181.15
Melting point
77-79°
Solubility
Insoluble in water.

Applications

4-Nitrophenyl acetate is used with iodoacetic acid for reductive cleavage of methionine-containing peptides. It is also used as a substrate that has been used in assays for esterase and lipase activity. Inorganic complexes have been evaluated for their methanolysis or hydrolysis activity using p-nitrophenyl acetate.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

John C. Hogan.; Richard D. Gandour. Fingerprinting a transition-structure guest by a building-block approach with an incremental series of catalytic hosts. Structural requirements for glyme and .alpha.,. µ. -dimethoxyalkane catalyses in N-methylbutylaminolysis and butylaminolysis of 4-nitrophenyl acetate in chlorobenzene. J. Org. Chem. 1992, 57, (1), 55-61.

Ik-Hwan Um.; Gwang-Ju Lee.; Hye-Won Yoon.; Dong-Sook Kwon. Solvent effect on rate for anionic nucleophilic substitution reaction of 4-nitrophenyl acetate in aqueous acetonitrile. Tetrahedron Letters. 1992, 33, (15), 2023-2026.

Reagent for the N-acylation of amines, e.g. basic amino acids: Can. J. Chem., 43, 991 (1965); 46, 1047 (1968).

Other References

Beilstein
515874
Harmonized Tariff Code
2915.39
TSCA
Yes
RTECS
AJ1150000

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