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Convenient and selective reagent for the selective formylation of terminal amino groups in such basic amino acids as ornithine or lysine and formylation of α-amino groups in peptides.
Dimitrios Stefanidis, et al. Structure-reactivity correlations for reactions of substituted phenolate anions with acetate and formate esters.J. Am. Chem. Soc.,1993,115,(5), 1650-1656.
Satyendra Kumar, et al. Production, purification, and characterization of lipase from thermophilic and alkaliphilic Bacillus coagulans BTS-3.Protein Expression and Purification.,2005,41,(1), 38-44.
Convenient and selective reagent for the formylation of amino groups: Bull. Chem. Soc. Jpn., 36, 754 (1963); Synthesis, 979 (1982); Synth. Commun., 29, 1819 (1999).
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.