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1865-01-6 - 4-Nitrophenyl formate, 98% - Formic acid 4-nitrophenyl ester - L00316 - Alfa Aesar

L00316 4-Nitrophenyl formate, 98%

CAS Number
1865-01-6
Synonyms
Formic acid 4-nitrophenyl ester

Size Price ($) Quantity Availability
5g 43.90
25g 161.00
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4-Nitrophenyl formate, 98%

MDL
MFCD00014713
EINECS
217-473-6

Chemical Properties

Formula
C7H5NO4
Formula Weight
167.12
Melting point
70-74°
Sensitivity
Moisture & Light Sensitive
Solubility
Hydrolyzes in water. Soluble in dichloromethane.

Applications

Convenient and selective reagent for the selective formylation of terminal amino groups in such basic amino acids as ornithine or lysine and formylation of α-amino groups in peptides.

Notes

Moisture and light sensitive. Store away from water/moisture, oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store in dark. Store under inert gas. Protect from exposure to light.

Literature References

Dimitrios Stefanidis, et al. Structure-reactivity correlations for reactions of substituted phenolate anions with acetate and formate esters.J. Am. Chem. Soc.,1993,115,(5), 1650-1656.

Satyendra Kumar, et al. Production, purification, and characterization of lipase from thermophilic and alkaliphilic Bacillus coagulans BTS-3.Protein Expression and Purification.,2005,41,(1), 38-44.

Convenient and selective reagent for the formylation of amino groups: Bull. Chem. Soc. Jpn., 36, 754 (1963); Synthesis, 979 (1982); Synth. Commun., 29, 1819 (1999).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1950897
Harmonized Tariff Code
2915.90
TSCA
Yes

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