Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

6065-82-3 - Ethyl diethoxyacetate, 97+% - Diethoxyacetic acid ethyl ester - Ethyl glyoxylate diethyl acetal - L00390 - Alfa Aesar

L00390 Ethyl diethoxyacetate, 97+%

CAS Number
6065-82-3
Synonyms
Diethoxyacetic acid ethyl ester
Ethyl glyoxylate diethyl acetal

Size Price ($) Quantity Availability
25g 58.00
100g 154.00
500g 470.00
Add to Cart Add to Quote Request View Item

Ethyl diethoxyacetate, 97+%

MDL
MFCD00009231
EINECS
227-999-8

Chemical Properties

Formula
C8H16O4
Formula Weight
176.21
Boiling Point
198-200°
Flash Point
85°(185°F)
Density
0.988
Refractive Index
1.4100
Solubility
Soluble in Dichloromethane, Ethyl Acetate and Methanol.

Applications

Ethyl diethoxyacetate is used in the preparation of a fatty acid analog containing DTS, 12,13-dioxotetradecanoic acid di(N-methyl-thiosemicarbazone) (FA-DTS). It is used for synthesis of heterocyclic compounds.

Notes

Store in cool, dry conditions in well sealed containers. Keep container tightly closed.

Literature References

Charles Heidelberger.; Robert B. Hurlbert. The Synthesis of Oxalacetic Acid-1-C14 and Orotic Acid-6-C14 1. J. Am. Chem. Soc. 1950, 72, (10), 4704-4706.

Fieser, L.F.; Dunn, J.T. Synthesis of Plumbagin. J. Am. Chem. Soc. 1936, 58, (4), 572-575.

Ethyl glyoxylate equivalent. Lithiation, e.g. with lithium diethylamide, provides a useful 2-carbon fragment: Tetrahedron Lett., 4551 (1975). Reaction with the bis-Grignard from 1,4-dibromobutane gives 1-(diethoxymethyl)cyclopentanol: Canad. J. Chem., 66, 168 (1988). See also Methyl­ dimethoxyacetate, A12171.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210u-P280a-P370+P378a-P403+P235-P501a

Wear protective gloves and eye/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
878579
Harmonized Tariff Code
2918.99
TSCA
Yes

Recommended

  • A10609

    2,3,4-Trimethoxybenzaldehyde, 98+%
  • A11113

    Ethyl formate, 97%
  • A12058

    Acetylacetaldehyde dimethyl acetal, tech. 90%
  • A13068

    Cyclobutanone, 98%, stab. with ca 0.01% BHT
  • A15261

    1,3-Propanedithiol, 97%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware